Search results for "Alta presión"
showing 6 items of 6 documents
Investigación de la estructura electrónica de láminas delgadas, pozos cuánticos y nanopartículas de Zn1-xCoxO mediante medidas ópticas y de transport…
2014
Dietl et al. Predijeron un comportamiento ferromagnético (FM) en compuestos de semiconductores magnéticos diluidos (DMS) de gap ancho como Ga1-xMnxN o Zn1-xCoxO. Las láminas delgadas de alta calidad basadas en los DMs de ZnO son de especial interés debido al bajo coste y la estabilidad del material. De esta manera, varios grupos han presentado que el comportamiento ferromagnético del Zn1-xCoxO a temperatura ambiente se debe a la existencia de diferentes fases o a agrupamientos pequeños de cobalto, especialmente para altas concentraciones de Co. De acuerdo con trabajos anteriores sobre el (Zn,Co)O , la transición de la fase wurtzita a la fase rock-salt en el material masivo y en las láminas …
High-pressure structural, elastic, and thermodynamic properties of zircon-type HoPO4 and TmPO4
2017
[EN] Zircon-type holmium phosphate (HoPO4) and thulium phosphate (TmPO4) have been studied by single-crystal x-ray diffraction and ab initio calculations. We report on the influence of pressure on the crystal structure, and on the elastic and thermodynamic properties. The equation of state for both compounds is accurately determined. We have also obtained information on the polyhedral compressibility which is used to explain the anisotropic axial compressibility and the bulk compressibility. Both compounds are ductile and more resistive to volume compression than to shear deformation at all pressures. Furthermore, the elastic anisotropy is enhanced upon compression. Finally, the calculation…
Structural and Vibrational Properties of Corundum-type In2O3 Nanocrystals under Compression
2017
[EN] This work reports the structural and vibrational properties of nanocrystals of corundum-type In2O3 (rh-In2O3) at high pressures by using angle-dispersive x-ray diffraction and Raman scattering measurements up to 30 GPa. The equation of state and the pressure dependence of the Raman-active modes of the corundum phase in nanocrystals are in good agreement with previous studies on bulk material and theoretical simulations on bulk rh-In2O3. Nanocrystalline rh-In2O3 showed stability under compression at least up to 20 GPa, unlike bulk rh-In2O3 which gradually transforms to the orthorhombic Pbca (Rh2O3-III-type) structure above 12 14 GPa. The different stability range found in nanocrystallin…
Optical and structural study of the pressure-induced phase transition of CdWO$_4$
2017
Physical review / B 95(17), 174105 (2017). doi:10.1103/PhysRevB.95.174105
High-pressure lattice-dynamics of NdVO4
2017
High-pressure Raman-scattering measurements and ab initio calculations on NdVO4 have been carried out up to 30 GPa. Our combined experimental and theoretical study confirms that beyond 5.9 GPa NdVO4 undergoes an irreversible zircon to monazite transition. The coexistence of zircon and monazite phases is experimentally observed up to ~8 GPa (which agrees with the theoretical transition pressure), stabilizing the monazite phase as a single phase around 10 GPa. Calculations additionally predict the existence of a second high-pressure phase transition at 12.4 GPa. This reversible phase transition has been experimentally observed beyond 18.1 GPa and remains stable up to 30 GPa. The post-monazite…
Polymorphism of rare-earth orthovanadates under high pressure
2022
Los ortovanadatos de tierras raras constituyen una familia paradigmática de óxidos ternarios, debido a sus llamativas propiedades y sus diferentes polimorfos. Una gran cantidad de sus diferentes fases pueden obtenerse sometiendo a estas estructuras cristalinas a condiciones de presión y temperatura extremas. En esta tesis se estudia el comportamiento de diferentes ortovanadatos (NdVO4, GdVO4, PrVO4 y TbVO4) bajo altas presiones y diferentes condiciones de temperatura. Varias muestras de estos compuestos han sido caracterizadas a través de diversas técnicas experimentales, entre las cuales se incluyen la difracción de rayos X (DRX), la dispersión Raman y la absorción óptica. Además de esto, …